Example: Thermal Equilibrium
A 300 gram block of aluminum at temperature 500 K is placed on a 650 gram block of iron at temperature 350 K in an insulated enclosure. At these temperatures the specific heat capacity of aluminum is approximately 1.0 J/K/gram, and the specific heat capacity of iron is approximately 0.42 J/K/gram. Within a few minutes the two metal blocks reach the same common temperature Tf. Calculate Tf.
Facts
Initial State: Different temperatures, not in contact
Final State: Blocks have come to thermal equilibrium, same Tf
300 gram block of aluminum which is at a temperature of 500 K
650 gram block of iron which is at a temperature of 350 K
Aluminum is placed on iron
Both in insulated enclosure
Specific heat capacity of aluminum is approximately 1.0 J/K/gram
Specific heat capacity of iron is approximately 0.42 J/K/gram
Metal blocks reach same temperature
Lacking
Tf common temperature
Approximations & Assumptions
Assume no other energy transfers.
Representations
System: The two blocks
Surroundings: Due to the insulation, no objects exchange energy with the chosen system
Energy Principle: ΔEAl+ΔEFe=0
ΔEsys=W
mCΔT=W
Solution
Due to the energy principle
ΔEAl+ΔEFe=0
The total energy of the two blocks does not change, because there is no energy transfer from or to the surroundings.
Therefore we want to solve for Tf which is the final temperature for both blocks.
m1C1(Tf−T1i)+m2C2(Tf−T2i)=0
Substitute in values for all known variables and solve for Tf.
(300g)(1.0J/K/g)(Tf−500)+(650g)(0.42J/K/g)(Tf−350)=0
Solving for the final temperature, we find Tf=429K.
In words, what happens in this process is that the aluminum temperature falls from 500 K to 429 K, and the iron temperature rises from 350 K to 429 K. The thermal energy decrease in the aluminum is equal to the thermal energy increase in the iron.